The possible synglaciogenic Ediacaran hematitic banded iron salt formation (BISF) at Hormuz Island,southern Iran: Implications for a new style of exhalative hydrothermal iron-salt system     

《Ore Geology Reviews》2017

The Ediacaran BISF at Hormuz Island is a newly identified glaciogenic iron-salt deposit in the Tethyan margin of Gondwana. The BISF was formed by synchronous riftogenic A-type submarine felsic volcanism and evaporate deposition. The mineralization occurs in a proximal felsic tuff cone and jaspilitic distal zones and contains 1 million tonne of hematite-rich ore with an average grade of 58% Fe. The ore structure shows cyclicity of macrobandings, mesobandings and microbandings of anhydrite, halite, hematite and chert, which marks a new record in BIFs geohistory. The alteration minerals in the proximal and distal zones are actinolite, ripidolite, epidote, sericite, tourmaline, clinochlore, anhydrite and clay minerals. The occurrence of metamorphosed polygenetic bullet-shape dropstones in BISF attests that there was probably a continuous process of ice melting, episodic submarine volcanism and exhalative hydrothermal banded iron salt formation during the Late Ediacaran time. The non-metamorphosed Neoproterozoic stratigraphy, the presence of genus Collenia, U-Pb dating (558 ± 7 Ma) and the marked negative δ¹³C excursion in cap carbonates are representative of Late Ediacaran glaciation, which has been identified worldwide. The REE+Y display light REE enrichment, unusually strong Tb-Tm anomaly, a weak positive Y anomaly, but no distinguished Eu and Ce anomalies, reflecting the glaciogenic nature of the BISF. The contents of Zr, Hf, Nb, Ta, Th, La, Ce and Y in BISF, dropstones, halite and cap carbonates are similar to those of the Neoproterozoic glaciogenic BIFs. Also, the Ni/Fe, P/Fe ratios and Fe/Ti – Al/Al + Fe + Mn + Ca + Na + K diagram suggest an exhalative hydrothermal Ediacaran-type BISF. The absence of brecciated magnetite in the ore association and the low contents of copper (9–493 ppm) and gold (<5–8 ppb) are not in favor of the IOCG – Kiruna-type iron oxide ores. The co-paragenesis of hematite with several alteration minerals, in particular actinolite, tourmaline and anhydrite, indicates that the exhalative hydrothermal fluids were generated by the interaction of seawater with the felsic rocks and sediments at about 200–500 °C. The interaction of seawater with felsic magma and sediments led to the formation of Mg-rich alteration minerals, leaching Si, Fe, Mn and other elements and forming the potential ore fluids. It is highlighted that the A-type alkaline submarine felsic volcanism could be considered as an exploration target for BISF.  相似文献   

Mineralogical,geochemical and Sr-Nd isotopes characteristics of fluorite-bearing granites in the Northern Arabian-Nubian Shield,Egypt: Constraints on petrogenesis and evolution of their associated rare metal mineralization     

《Ore Geology Reviews》2017

The Central Eastern Desert (CED) of Egypt, a part of Neoproterozoic Arabian Nubian Shield (ANS), embraces a multiplicity of rare metal bearing granitoids. Gabal El-Ineigi represents one of these granitic plutons and is a good example of the fluorite-bearing rare metal granites in the ANS. It is a composite pluton consisting of a porphyritic syenogranite (SG; normal granite) and coarse- to medium-grained highly evolved alkali-feldspar granite (AFG; fluorite and rare metal bearing granite) intruded into older granodiorite and metagabbro-diorite rocks. The rock-forming minerals are quartz, K-feldspar (Or_94-99), plagioclase (An_0-6) and biotite (protolithonite-siderophyllite) in both granitic types, with subordinate muscovite (Li-phengite) and fluorite in the AFG. Columbite-(Fe), fergusonite-(Y), rutile, zircon and thorite are the main accessory phases in the AFG while allanite-(Ce) and epidote are exclusively encountered in the SG. Texture and chemistry of minerals, especially fluorite, columbite and fergusonite, support their magmatic origin. Both granitic types are metaluminous to weakly peraluminous (A/CNK = 0.95–1.01) and belong to the post-collisional A2-type granites, indicating melting of underplated mafic lower crust. The late phase AFG has distinctive geochemical features typical of rare metal bearing granites; it is highly fractionated calc-alkaline characterized by high Rb, Nb, Y, U and many other HFSE and HREE contents, and by extremely low Sr and Ba. Moreover, the REE patterns show pronounced negative Eu anomalies (Eu/Eu¹ = 0.03 and 0.06) and tetrad effect (TE_1,3 = 1.13 and 1.27), implying extensive open system fractionation via fluid–rock interactions that characterize the late magmatic stage differentiation. The SG is remarkably enriched in Sr, Ba and invariably shows a relative enrichment in light rare-earth elements (LREEs). The SG rocks (569 ± 15 Ma) are characterized by relatively low initial ⁸⁷Sr/⁸⁶Sr ratios (0.7034–0.7035) that suggest their derivation from the mantle, with little contamination from the older continental crust. By contrast, the AFG has very high ⁸⁷Rb/⁸⁶Sr and ⁸⁷Sr/⁸⁶Sr ratios that reflect the disturbance of the Rb-Sr isotopic system and may give an indication for the high temperature magma-fluid interaction. The positive εNd(t) values of AFG (+7.40) and SG (+5.17), corresponding to young Nd-T_DM2 ages ranging from 707 to 893 Ma, clearly reflect the juvenile crustal nature of Gabal El-Ineigi granitoids and preclude the occurrence of pre-Neoproterozoic continental crust in the ANS. The field relationships, chemical, petrological and isotopic characteristics of El-Ineigi SG and AFG prove that they are genetically not associated to each other and indicate a complex origin involving two compositionally distinct parental magmas that were both modified during magmatic fractionation processes. We argue that the SG was formed by partial melting of a mid-crustal source with subsequent fractional crystallization. In contrast, the AFG was generated by partial melting and fractionation of Nb- and Ta-rich amphibole (or biotite) of the lower crust. The appreciable amounts of fluorine in the magma appears to be responsible for the formation of rare metal element complexes (e.g., Nb, Ta, Sn and REEs), and could account for the rare metal mineralization in the El-Ineigi AFG.  相似文献   

华北地块西南缘古元古代花岗斑岩及其构造意义   总被引：1，自引：0，他引：1       下载免费PDF全文

尤佳  罗金海  程佳孝  王师迪  徐欢  赵慧 《高校地质学报》2014,20(3):368

在六盘山南段陇县固关镇东部出露多个原认为属于中-新生代的花岗斑岩岩体,其中的白家沟花岗斑岩显示古元古 代壳源岩浆活动的记录,属于钙碱性花岗岩系。该花岗斑岩高SiO2 （71.14%~73.33%）,高碱（Na2O+ K2O=7.61%~8.70%）, 富钾（K2O/Na2O=1.21~2.52,平均为2.03）,具有准铝-弱过铝质特点（铝饱和指数A/CNK=0.93~1.09,平均1.00）。稀土元 素配分曲线呈轻稀土强烈富集的典型“海鸥型”样式,具有明显的Eu负异常（δEu=0.44~0.47）。岩石富集大离子亲石元素 K,Rb,Ba,Th,亏损高场强元素Ti,Nb,Ta,具有壳源A型花岗岩的地球化学特征。对该花岗斑岩进行的锆石U-Pb LA-ICP-MS同位素年代测定获得了1 846±32 Ma的上交点年龄,说明花岗斑岩形成于古元古代而不是前人认为的中-新生 代,上奥陶统背锅山组砾屑灰岩实际上是沉积于古元古代花岗斑岩之上。结合区域地质资料研究结果表明华北地块西南缘 在古元古代时期处于强烈的伸展环境,这可能为古元古代贺兰坳拉槽向南延伸至六盘山南段提供了直接的岩石学证据。  相似文献   

中天山天湖东铁钼矿含矿片麻状花岗岩年代学、地球化学和锆石Hf同位素-对于中天山早古生代构造演化的启示     

雷如雄  吴昌志  屈迅  顾连兴  陈刚  吾尔娜  孙洪涛  刘国宁 《吉林大学学报(地球科学版)》2014,44(5):1540-1552

以中天山东段的天湖东铁钼矿含矿花岗岩为例,在LA-ICP-MS锆石U-Pb年代学测定其为早古生代花岗岩（（445.3±4.6） Ma）基础上,通过岩相学、地球化学及锆石原位Hf同位素组成等多方面研究,探讨该岩体的成岩作用及其构造背景。天湖东含矿片麻状花岗岩的主要矿物为斜长石、石英、钾长石,并含少量黑云母和角闪石等。全岩地球化学分析结果表明,该片麻状花岗岩高硅、弱富铝、富钙、富钠而贫钾,ASI值为0.68~0.82,属于准铝质钙碱性花岗岩,总体上富集大离子亲石元素（LILE）Rb、Ba等和轻稀土元素La、Ce、Nd等,而亏损高场强元素Nb、Ta、Ti、Yb等,轻重稀土分异明显,轻稀土分异较为明显,而重稀土分异不明显,表现出典型岛弧岩浆岩的地球化学特征。锆石的ε_Hf(445 Ma)值为-6.31~-1.77,二阶段Hf模式年龄（T_DM2）为1.538~1.825 Ga,表明该花岗岩的源区主要为壳源物质。综合分析上述资料,认为天湖东铁钼矿片麻状花岗岩是由俯冲过程中地壳物质重熔的产物。结合前人的研究和本课题组的新近研究成果认为,在早古生代时,中天山为岩浆弧构造环境,形成一系列的钙碱性岩浆岩,而该岩浆弧的形成可能是受到介于吐哈陆块和塔里木板块之间的古天山大洋在早古生代时期向南俯冲而形成的。  相似文献   

东准噶尔贝勒库都克铝质A型花岗岩微量元素地球化学特征及地质意义   总被引：4，自引：0，他引：4  

杨高学  李永军  司国辉  吴宏恩  张永智  金朝 《地球科学与环境学报》2010,32(1):34-39

通过对新疆东准噶尔卡拉麦里地区贝勒库都克岩体的岩石地球化学特征的研究,结果表明,在贝勒库都克黑云母花岗岩中Rb、K和Th等大离子亲石元素明显富集,相对富集Zr、Hf等高场强元素,相对亏损Ba、Sr、Nb和Eu等元素,稀土元素含量相对较高,Eu的负异常极强,稀土元素配分模式呈平坦的"V"字型,属于典型的铝质A型花岗岩。该花岗岩在成因上属于A2型,形成于后碰撞的张性环境,其来源可能与洋壳和岛弧建造组成的年轻地壳有关。花岗岩微量元素构造判别图显示它是一种后碰撞花岗岩,标志卡拉麦里地区在晚石炭世造山作用的结束和板内构造演化的开始。该岩体锡质量分数普遍都比较高(15.50 10-6),为锡的成矿物质来源和锡矿矿床学的深入探索提供重要参考。  相似文献   

Contrasting origins of Cenozoic silicic volcanic rocks from the western Cordillera of the United States   总被引：2，自引：0，他引：2  

Eric H. Christiansen  Michael McCurry 《Bulletin of Volcanology》2008,70(3):251-267

Two fundamentally different types of silicic volcanic rocks formed during the Cenozoic of the western Cordillera of the United States. Large volumes of dacite and rhyolite, mostly ignimbrites, erupted in the Oligocene in what is now the Great Basin and contrast with rhyolites erupted along the Snake River Plain during the Late Cenozoic. The Great Basin dacites and rhyolites are generally calc-alkaline, magnesian, oxidized, wet, cool (<850°C), Sr-and Al-rich, and Fe-poor. These silicic rocks are interpreted to have been derived from mafic parent magmas generated by dehydration of oceanic lithosphere and melting in the mantle wedge above a subduction zone. Plagioclase fractionation was minimized by the high water fugacity and oxide precipitation was enhanced by high oxygen fugacity. This resulted in the formation of Si-, Al-, and Sr-rich differentiates with low Fe/Mg ratios, relatively low temperatures, and declining densities. Magma mixing, large proportions of crustal assimilation, and polybaric crystal fractionation were all important processes in generating this Oligocene suite. In contrast, most of the rhyolites of the Snake River Plain are alkaline to calc-alkaline, ferroan, reduced, dry, hot (830–1,050°C), Sr-and Al-poor, and Nb-and Fe-rich. They are part of a distinctly bimodal sequence with tholeiitic basalt. These characteristics were largely imposed by their derivation from parental basalt (with low fH₂O and low fO₂) which formed by partial melting in or above a mantle plume. The differences in intensive parameters caused early precipitation of plagioclase and retarded crystallization of Fe–Ti oxides. Fractionation led to higher density magmas and mid-crustal entrapment. Renewed intrusion of mafic magma caused partial melting of the intrusive complex. Varying degrees of partial melting, fractionation, and minor assimilation of older crust led to the array of rhyolite compositions. Only very small volumes of distinctive rhyolite were derived by fractional crystallization of Fe-rich intermediate magmas like those of the Craters of the Moon-Cedar Butte trend. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

南岭地区钨矿床共（伴）生金属特征及其地质意义初探   总被引：8，自引：0，他引：8  

华仁民  张文兰  李光来  胡东泉  王旭东 《高校地质学报》2008,14(4):527-538

南岭是世界上最重要的钨矿产地,南岭钨矿床中与钨共（伴）生的有色、稀有及贵金属种类很多,数量可观,也是我国重要的矿产资源。论述了南岭及其邻近地区众多钨矿床中与钨共生或伴生的锡、钼、铋、铌钽、铜、铅锌、金银、稀土等元素的不同状况和特征,其中锡、钼、铋是南岭钨矿床中最普遍最重要的共（伴）生元素,铌钽只在演化程度较高的花岗岩相关的钨矿床中伴生产出,铜、金作为钨矿床伴生金属的意义较小,而钨矿床中伴生的银、铅锌具有相当重要的意义。从元素地球化学性质、南岭的区域地背景、花岗岩演化、多期多阶段成矿作用等方面出发,分析和解释了它们之间相互共（伴）生的原因及差异性,探讨了其地质意义。  相似文献   

内蒙古扎鲁特旗三叠纪黑云母二长花岗岩特征   总被引：1，自引：0，他引：1  

李晓海  姚玉来  李文博  张海华 《地质与资源》2016,25(1):11-16

内蒙古扎鲁特旗北部黑云母二长花岗岩岩体位于兴蒙造山带东段,形成于晚三叠世.黑云母二长花岗岩岩石地球化学表现为富SiO₂、Al₂O₃和碱质,Na₂O/K₂O比值小于1,A/CNK比值介于1.021~1.084之间,轻重稀土元素分馏明显,轻稀土元素富集,具明显负铕异常.微量元素中亏损Ba、Sr、Ti、P,稀土元素中亏损Eu、Yb,具有A型花岗岩的地球化学特征.结合区域地质资料和前人相关研究,推测黑云母二长花岗岩可能形成于板块内部造山后期地壳伸展减薄的环境.  相似文献   

浙江中部芙蓉山花岗斑岩及包体岩石地球化学研究     

杜秀玲  汪方跃  闫海洋  顾海欧  孙贺  葛粲 《地质论评》2022,68(1):18-46

花岗岩的源区、温压条件及与其他岩石的共生组合的研究可以限定其形成构造背景,了解其形成的深部动力学过程.本文对浙江中部中生代芙蓉山花岗斑岩及其暗色包体开展了全岩主微量元素、锆石U-Pb年代学和Hf同位素、Ti温度计和全岩Sr—Nd同位素研究,探讨芙蓉山花岗斑岩的成因类型、源区特征及其与镁铁质包体之间的关系,并进一步限定其...  相似文献   

南天山拜城县波孜果尔A型花岗岩类锆石U-Pb定年及其Lu-Hf同位素组成   总被引：3，自引：2，他引：1  

刘春花  吴才来  郜源红  雷敏  秦海鹏  李名则 《岩石学报》2014,30(6):1595-1614

新疆拜城县波孜果尔A型花岗岩类岩体位于塔里木地台北缘及邻区的近东西向碱性侵入岩带上,主要岩石类型为霓石钠闪石英碱长正长岩、霓石钠闪碱长花岗岩、黑云母碱长正长岩。全岩SiO₂=68.97%~74.14%,Na₂O+K₂O=9.67%~11.19%,Al₂O₃=13.72%~15.26%,Fe₂O₃=0.18%~1.41%,FeO=0.91%~1.51%,CaO=0.35%~0.63%。稀土元素总量较高,ΣREE=298×10^-6~1286×10^-6,平均706×10^-6,轻稀土富集,重稀土亏损,强烈的Eu负异常,呈“右倾海鸥型”的稀土元素配分模式。富Nb、Ta、Zr、Hf等高场强元素,亏损Ba、K、Sr等大离子亲石元素,Zr+Nb+Ce+Y=936×10^-6~3684×10^-6,平均1813×10^-6。为A1型花岗岩。岩体形成于早二叠纪。锆石LA-ICP-MS U-Pb年龄为287.7~291.6Ma,平均289.8Ma,岩体形成后,在279.1~282Ma左右经历了后期热液流体的改造。锆石ε_Hf（t）值为-6.3~9.0,两阶段模式年龄（t_DM2）跨越古元古代晚期-新元古代中期,主要集中在中元古代。岩浆平均温度832~839℃,形成于非造山的板内构造环境,且具高温、无水、低氧逸度的成岩特点。该岩体具有壳幔混源的特点。  相似文献